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JEE Main 202331 JanuaryEvening Shift
Exam
JEE Main
Year
2023
Date
31 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Solutions

JEE Main 2023 · 31 January · Evening Shift · Chemistry · Solutions

Evaluate the following statements for their correctness. A. The...

Evaluate the following statements for their correctness.

A. The elevation in boiling point temperature of water will be same for 0.1M0 . 1M NaClNaCl and 0.1M0 . 1M urea.
B. Azeotropic mixture boil without change in their composition.
C. Osmosis always takes place from hypertonic to hypotonic solution.
D. The density of 3232 % H2SO4{H}_{2}{SO}_{4} solution having molarity 4.09M4 . 09M is approximately 1.26gmL–11 . 26g{mL}^{– 1}.
E. A negatively charged sol is obtained when KIKI solution is added to silver nitrate solution.

Choose the correct answer from the options given below:

Options

  1. AB and D only
  2. BB, D and E only
  3. CA and C only
  4. DA, B and C only

Correct answer

A. B and D only

Step-by-step solution

(A) Elevation in boiling point (∆Tb∆ {T}_{b}) temperature of the water is not same, as ‘ii’ value is different for two solutions.
(B) Azeotropic mixture: Liquid mixtures that distill over without changes in composition are called constant boiling mixtures or Azeotropes or Azeotropic mixtures.
(C) Osmosis always takes place from hypotonic (low concentration of solute) solution to hypertonic (high concentration of solute) solution.
(D) Let the mass of H2SO4{H}_{2}{SO}_{4} (3232 %) is 100.

∴∴ Weight of H2SO4=32{H}_{2}{SO}_{4}=32

Moles of H2SO4=3298{H}_{2}{SO}_{4} = \dfrac{32}{98}

Now, 4.09=3298×V4 . 09 = \dfrac{32}{98 \times V}

⇒V=79mL⇒ V = 79mL

Density = 10079=1.265\dfrac{100}{79} = 1 . 265
(E) A negative charged sol is obtained when KIKI solution is added to silver nitrate solution whereas positive charged sol is obtained when AgNO3{AgNO}_{3} solution is added to KIKI solution.

So, the correct answer is B and D only.

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