JEE Main 202324 JanuaryEvening Shift
- Exam
- JEE Main
- Year
- 2023
- Date
- 24 January
- Shift
- Evening Shift
- Subject
- Chemistry
- Chapter
- Solutions
JEE Main 2023 · 24 January · Evening Shift · Chemistry · Solutions
The Total pressure observed by mixing two liquid AandB is 350mmHg...
The Total pressure observed by mixing two liquid is when their mole fractions are respectively. The Total pressure becomes if the mole fractions are changed to respectively for . The vapour pressure of pure is ______ . (Nearest integer) Consider the liquids and solutions behave ideally
Correct answer
0
Step-by-step solution
Let Vapour pressure of pure be
Let Vapour pressure of pure be
Using Raoult's law and Dalton's law:
When{X}_{A} = 0 . 7 \text{ and } {X}_{B} = 0 . 3{P}_{s} = 350 ⇒ {P}_{A}^{o} \times 0 . 7 + {P}_{B}^{o} \times 0 . 3 = 350 . . . . ( i ) When{X}_{A} = 0 . 2 \text{ and } {X}_{B} = 0 . 8{P}_{s} = 410 ⇒ {P}_{A}^{o} \times 0 . 7 + {P}_{B}^{o} \times 0 . 3 = 350 . . . . ( ii ) Solving ( i ) and ( ii ) {P}_{A}^{o} = 314mmHg{P}_{B}^{o} = 434mmHg$