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JEE Main 202324 JanuaryEvening Shift
Exam
JEE Main
Year
2023
Date
24 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Solutions

JEE Main 2023 · 24 January · Evening Shift · Chemistry · Solutions

The Total pressure observed by mixing two liquid AandB is 350mmHg...

The Total pressure observed by mixing two liquid AandBA\text{and}B is 350mmHg350mmHg when their mole fractions are 0.7and0.30 . 7\text{and}0 . 3 respectively. The Total pressure becomes410mmHg410mmHg if the mole fractions are changed to0.2and0.80 . 2\text{and}0 . 8 respectively for AandBA\text{and}B. The vapour pressure of pure AA is ______ mmHgmmHg. (Nearest integer) Consider the liquids and solutions behave ideally

Correct answer

0

Step-by-step solution

Let Vapour pressure of pure AA be PAo{P}_{A}^{o}

Let Vapour pressure of pure BB be PBo{P}_{B}^{o}

Using Raoult's law and Dalton's law:

When{X}_{A} = 0 . 7 \text{ and } {X}_{B} = 0 . 3{P}_{s} = 350 ⇒ {P}_{A}^{o} \times 0 . 7 + {P}_{B}^{o} \times 0 . 3 = 350 . . . . ( i ) When{X}_{A} = 0 . 2 \text{ and } {X}_{B} = 0 . 8{P}_{s} = 410 ⇒ {P}_{A}^{o} \times 0 . 7 + {P}_{B}^{o} \times 0 . 3 = 350 . . . . ( ii ) Solving ( i ) and ( ii ) {P}_{A}^{o} = 314mmHg{P}_{B}^{o} = 434mmHg$

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