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JEE Main 202324 JanuaryMorning Shift
Exam
JEE Main
Year
2023
Date
24 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Solutions

JEE Main 2023 · 24 January · Morning Shift · Chemistry · Solutions

When Fe _ 0 . 93 O is heated in presence of oxygen, it converts to...

When Fe0.93O{Fe}_{0 . 93}O is heated in presence of oxygen, it converts to Fe2O3{Fe}_{2}{O}_{3}. The number of correct statement/s from the following is ______ .

A. The equivalent weight of Fe0.93O{Fe}_{0 . 93}O is Molecularweight0.79\dfrac{Molecularweight}{0 . 79}

B. The number of moles of Fe2+{Fe}^{2 +} and Fe3+{Fe}^{3 +} in 11 mole of Fe0.93O{Fe}_{0 . 93}O is 0.790 . 79 and 0.140 . 14 respectively.

C. Fe0.93O{Fe}_{0 . 93}O is metal deficient with lattice comprising of cubic closed packed arrangement of O2−{O}^{2 -} ions.

D. The % composition of Fe2+{Fe}^{2 +} and Fe3+{Fe}^{3 +} in Fe0.93O{Fe}_{0 . 93}O is 8585 % and 1515 % respectively.

Correct answer

0

Step-by-step solution

A:Fe0.93O→Fe2O3A: {Fe}_{0 . 93}O \to {Fe}_{2}{O}_{3}

The valence factor of Fe0.93O{Fe}_{0 . 93}O, nf=(3−20093)×0.93nf = \left(3 - \dfrac{200}{93}\right) \times 0 . 93

nf=0.79nf = 0 . 79

Hence, the equivalent weight =Molecularweight0.79= \dfrac{Molecularweight}{0 . 79}

B:2x+(0.93−x)×3=2B: 2x + \left(0 . 93 - x\right) \times 3 = 2

x=0.79x = 0 . 79

Fe2+=0.79,Fe3+=0.14{Fe}^{2 +} = 0 . 79, {Fe}^{3 +} = 0 . 14

C:C: In Fe0.93O{Fe}_{0 . 93}O, O2−{O}^{2 -} ions forms the lattice and iron ions occupies the voids in the lattice. As sufficient number of irons are not available, this metal oxide is said to be metal difficient.

D:D: % {Fe}^{2 +} = \dfrac{0 . 79}{0 . 93} \times 100 = 85 % ; {Fe}^{3 +} = 15 %

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