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JEE Main 202229 JuneEvening Shift
Exam
JEE Main
Year
2022
Date
29 June
Shift
Evening Shift
Subject
Chemistry
Chapter
Solutions

JEE Main 2022 · 29 June · Evening Shift · Chemistry · Solutions

Elevation in boiling point for 1 . 5 molal solution of glucose in...

Elevation in boiling point for 1.51 . 5 molal solution of glucose in water is 4K4K. The depression in freezing point for 4.54 . 5 molal solution of glucose in water is 4K4K. The ratio of molal elevation constant to molal depression constant (Kb/Kf)\left({K}_{b} / {K}_{f}\right) is

Correct answer

3

Step-by-step solution

Elevation in boiling point ∆Tb=ikbm1∆ {T}_{b} = {ik}_{b}{m}_{1}

Depression in freezing point ∆Tf=ikfm2∆ {T}_{f} = {ik}_{f}{m}_{2}

4=ikb(1.5)4 = {ik}_{b}\left(1 . 5\right)

4=ikf(4.5)4 = {ik}_{f}\left(4 . 5\right)

Dividing both:

kbkf=31\dfrac{{k}_{b}}{{k}_{f}} = \dfrac{3}{1}

Hence, The ratio of molal elevation constant to molal depression constant is 3:1

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