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JEE Main 202127 JulyEvening Shift
Exam
JEE Main
Year
2021
Date
27 July
Shift
Evening Shift
Subject
Chemistry
Chapter
Solutions

JEE Main 2021 · 27 July · Evening Shift · Chemistry · Solutions

In a solvent 50 % of an acid HA dimerizes and the rest dissociates....

In a solvent 5050 % of an acid HA dimerizes and the rest dissociates. The van't Hoff factor of the acid is _____×10−2\times {10}^{- 2} (Round off to the nearest integer)

Correct answer

0

Step-by-step solution

Let initial moles of HAHA is aa

2HA→H2A20.5a0.25a2HA \to {H}_{2}{A}_{2}0 . 5a0 . 25a

HA⇌H++A−0.5a0.5a0.5aHA ⇌ {H}^{+} + {A}^{-}0 . 5a0 . 5a0 . 5a

Now, i=final molesinitial moles=0.25a+0.5a+0.5a0.5a+0.5ai = \dfrac{\text{final moles}}{\text{initial moles}} = \dfrac{0 . 25a + 0 . 5a + 0 . 5a}{0 . 5a + 0 . 5a}

=1.25=125×10−2= 1 . 25 = 125 \times {10}^{- 2}

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