Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main 202126 AugustMorning Shift
Exam
JEE Main
Year
2021
Date
26 August
Shift
Morning Shift
Subject
Chemistry
Chapter
Solutions

JEE Main 2021 · 26 August · Morning Shift · Chemistry · Solutions

Of the following four aqueous solutions, the total number of those...

Of the following four aqueous solutions, the total number of those solutions whose freezing point is lower than that of 0.10MC2H5OH0 . 10{MC}_{2}{H}_{5}OH is (Integer answer)
(i) 0.10MBa3(PO4)20 . 10M{Ba}_{3}{\left({PO}_{4}\right)}_{2}
(ii) 0.10MNa2SO40 . 10M{Na}_{2}{SO}_{4}
(iii) 0.10MKCl0 . 10MKCl
(iv) 0.10MLi3PO40 . 10M{Li}_{3}{PO}_{4}

Correct answer

4

Step-by-step solution

ΔTf=ikfm{\Delta T}_{f} = {ik}_{f}m

As mm is the same for all solutions so ΔTf{\Delta T}_{f} depends on Van't Hoff factor (i). Greater is i small is freezing point.

{CompoundiC2H5OH1Ba3(PO4)25Na2SO43KCl2Li3PO44\begin{cases}\text{Compound} & \text{i} \\ {C}_{2}{H}_{5}OH & 1 \\ {Ba}_{3}{\left({PO}_{4}\right)}_{2} & 5 \\ {Na}_{2}{SO}_{4} & 3 \\ KCl & 2 \\ {Li}_{3}{PO}_{4} & 4\end{cases}

So the given solutions have a lower freezing point than ethanol.

Practice Solutions on Quantrex Academy →

More from Solutions

In a solvent S , a compound B is partially dissociated into C and D as given below: B… JEE Advanced 2026Passage: Two volatile liquids A and B form an ideal solution. Consider a 5 molal solution… JEE Advanced 2026Passage: Two volatile liquids A and B form an ideal solution. Consider a 5 molal solution… JEE Advanced 2026Given below are two statements: Given: Molar mass of C, H, O, Cl are 12, 1, 16 and 35.5 g… JEE Main 2026Which of the following statements are not correct? A. For water, magnitude of K_b is more… JEE Main 2026Given below are two statements : Statement I : H _2 O molecules move from the chamber 1… JEE Main 2026When 0.25 moles of a non-volatile, non-ionizable solute was dissolved in 1 mole of a… JEE Main 202620 g hemoglobin in a 1 L aqueous solution (A) at 300 K is separated from pure water by… JEE Main 2026 Full Solutions list All JEE Main PYQs