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JEE Main 20206 SeptemberMorning Shift
Exam
JEE Main
Year
2020
Date
6 September
Shift
Morning Shift
Subject
Chemistry
Chapter
Solutions

JEE Main 2020 · 6 September · Morning Shift · Chemistry · Solutions

The elevation of boiling point of 0 . 10m aqueous CrCl _ 3 . xNH _...

The elevation of boiling point of 0.10m0 . 10m aqueous CrCl3.xNH3{CrCl}_{3} . {xNH}_{3} solution is two times that of 0.05m0 . 05m aqueous CaCl2{CaCl}_{2} solution. The value of xx is …………..\ldots \ldots \ldots \ldots . .
[Assume 100100 % ionisation of the complex and CaCl2,{CaCl}_{2}, coordination number of CrCr as 6,6, and that all NH3{NH}_{3} molecules are present inside the coordination sphere]

Correct answer

0

Step-by-step solution

0.05m0 . 05m aqueous CaCl2{CaCl}_{2} =0.15= 0 . 15molal solution of non electrolyte

Since the elevation in boiling point is double so the molality of given solution of complex =0.3m= 0 . 3m

Hence the complex must be producing three ions in the solution, so its formula =[Cr(NH3)5Cl]Cl2= \left[Cr{\left({NH}_{3}\right)}_{5}Cl\right]{Cl}_{2}

SO X=5X = 5

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