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JEE Main 201911 JanuaryMorning Shift
Exam
JEE Main
Year
2019
Date
11 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Solutions

JEE Main 2019 · 11 January · Morning Shift · Chemistry · Solutions

The freezing point of a diluted milk sample is found to be -0.2^ C,...

The freezing point of a diluted milk sample is found to be −0.2∘C,-0.2^{\circ} \mathrm{C}, while it should have been −0.5∘C-0.5^{\circ} \mathrm{C} for pure milk. How much water has been added to pure milk to make the diluted sample?

Options

  1. A1 cup of water to 2 cups of pure milk
  2. B3 cups of water to 2 cups of pure milk
  3. C1 cup of water to 3 cups of pure milk
  4. D2 cups of water to 3 cups of pure milk

Correct answer

B. 3 cups of water to 2 cups of pure milk

Step-by-step solution

Freezing point of diluted milk =−0.2∘CΔTf∗==-0.2^{{}^{\circ}} \mathrm{C}\Delta \mathrm{T}_{\mathrm{f}}^{*}=0.2^{{}^{\circ}} C\mathrm{C}Free ring point ol pure milk =−0.5∘CΔTf==-0.5^{{}^{\circ}} \mathrm{C}\Delta \mathrm{T}_{\mathrm{f}}=0.5^{{}^{\circ}} CΔTfΔTf′=Kf×m Kf×m′;m= mole of solute  mass of solvent (kg)\mathrm{C}\frac{\Delta \mathrm{T}_{\mathrm{f}}}{\Delta \mathrm{T}_{\mathrm{f}}^{\prime}}=\frac{\mathrm{K}_{\mathrm{f}} \times m}{\mathrm{~K}_{\mathrm{f}} \times m^{\prime}} ; m=\frac{\text{ mole of solute }}{\text{ mass of solvent }(\mathrm{kg})} Moles of solute are same in both samples. \therefore 0.50.2=Wn WW′W=52;W′=52 W\frac{0.5}{0.2}=\frac{\mathrm{W}^{n}}{\mathrm{~W}}\frac{\mathrm{W}^{\prime}}{\mathrm{W}}=\frac{5}{2} ; \mathrm{W}^{\prime}=\frac{5}{2} \mathrm{~W} 2 cups of pure milk is mixed with 3 cups of water to make 5 cups of diluted milk.
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