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JEE Main 20264 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
4 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Structure of Atom

JEE Main 2026 · 4 April · Morning Shift · Chemistry · Structure of Atom

What is the ratio of wave number of first line (lowest energy line)...

What is the ratio of wave number of first line (lowest energy line) of Balmer series of H atomic spectrum to first line of its Brackett series?

Options

  1. A5:15:1
  2. B5:0.815:0.81
  3. C5:1.755:1.75
  4. D5:275:27

Correct answer

B. 5:0.815:0.81

Step-by-step solution

The wave number νˉ\bar{\nu} of a spectral line in the hydrogen emission spectrum is given by the Rydberg formula:

νˉ=RH(1n12−1n22)\bar{\nu} = R_H \left( \dfrac{1}{n_1^2} - \dfrac{1}{n_2^2} \right)

For the first line (lowest energy) of the Balmer series, the transition is from n2=3n_2 = 3 to n1=2n_1 = 2:

νˉBalmer=RH(122−132)=RH(14−19)=5RH36\bar{\nu}_{Balmer} = R_H \left( \dfrac{1}{2^2} - \dfrac{1}{3^2} \right) = R_H \left( \dfrac{1}{4} - \dfrac{1}{9} \right) = \dfrac{5R_H}{36}

For the first line of the Brackett series, the transition is from n2=5n_2 = 5 to n1=4n_1 = 4:

νˉBrackett=RH(142−152)=RH(116−125)=9RH400\bar{\nu}_{Brackett} = R_H \left( \dfrac{1}{4^2} - \dfrac{1}{5^2} \right) = R_H \left( \dfrac{1}{16} - \dfrac{1}{25} \right) = \dfrac{9R_H}{400}

Taking the ratio of the two wave numbers:

νˉBalmerνˉBrackett=5RH369RH400=536×4009=50081\dfrac{\bar{\nu}_{Balmer}}{\bar{\nu}_{Brackett}} = \dfrac{\dfrac{5R_H}{36}}{\dfrac{9R_H}{400}} = \dfrac{5}{36} \times \dfrac{400}{9} = \dfrac{500}{81}

To express this ratio in the form 5:x5 : x, we divide the numerator and the denominator by 100100:

50081=50.81\dfrac{500}{81} = \dfrac{5}{0.81}

The ratio is 5:0.815 : 0.81.

Answer: 5:0.815:0.81
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