Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main 202621 JanuaryMorning Shift
Exam
JEE Main
Year
2026
Date
21 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Structure of Atom

JEE Main 2026 · 21 January · Morning Shift · Chemistry · Structure of Atom

Given below are two statements : Statement I : When an electric...

Given below are two statements :
Statement I: When an electric discharge is passed through gaseous hydrogen, the hydrogen molecules dissociate and the energetically excited hydrogen atoms produce electromagnetic radiation of discrete frequencies.
Statement II: The frequency of second line of Balmer series obtained from He+\mathrm{He}^{+}is equal to that of first line of Lyman series obtained from hydrogen atom.
In the light of the above statements, choose the correct answer from the options given below :

Options

  1. AStatement I is false but Statement II is true
  2. BBoth Statement I and Statement II are true
  3. CStatement I is true but Statement II is false
  4. DBoth Statement I and Statement II are false

Correct answer

B. Both Statement I and Statement II are true

Step-by-step solution

Statement I: Electric discharge through H2H_2 causes dissociation into excited H atoms which emit discrete frequencies (line spectrum). This is true.
Statement II: Using ν=RcZ2(1n12−1n22)\nu = RcZ^2\left(\frac{1}{n_1^2} - \frac{1}{n_2^2}\right)
For He+He^+ (Z=2), second Balmer line (n1=2,n2=4n_1=2, n_2=4): ν=4Rc(14−116)=3Rc4\nu = 4Rc\left(\frac{1}{4} - \frac{1}{16}\right) = \frac{3Rc}{4}
For H (Z=1), first Lyman line (n1=1,n2=2n_1=1, n_2=2): ν=Rc(1−14)=3Rc4\nu = Rc\left(1 - \frac{1}{4}\right) = \frac{3Rc}{4}
Both frequencies are equal. Statement II is true.
Both statements are true.
Practice Structure of Atom on Quantrex Academy →

More from Structure of Atom

The 2s and the 2p orbital energies of hydrogen atom are E_ 2s (H) and E_ 2p (H)… JEE Advanced 2026X^ a+ and Y^ b+ are hydrogen-like species. The wavelength of light absorbed during the… JEE Advanced 2026Consider two radiations of wavelengths 1. λ_1 = 2000 Å 2. λ_2 = 6000 Å The ratio of the… JEE Main 2026The Bohr radius of a hydrogen like species is 70.53 pm. The species and the stationary… JEE Main 2026If shortest wavelength of hydrogen atom in Lyman series is x , then longest wavelength in… JEE Main 2026Match the LIST-I with LIST-II List-I Orbital List-II Radial nodes and nodal plane A. 2s… JEE Main 2026Which of the following statement(s) is/are true ? A. If two orbitals have the same value… JEE Main 2026Arrange the following atomic orbitals of multi electron atoms in order of increasing… JEE Main 2026 Full Structure of Atom list All JEE Main PYQs