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JEE Main 202312 AprilMorning Shift
Exam
JEE Main
Year
2023
Date
12 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Structure of Atom

JEE Main 2023 · 12 April · Morning Shift · Chemistry · Structure of Atom

Given below are two statement : one is labelled as Assertion A and...

Given below are two statement : one is labelled as Assertion A and the other is labelled as Reason R

Assertion A : 5f5f electron can participate in bonding to a far greater extent than 4f4f electrons

Reason R : 5f5f orbitals are not as buried as 4f4f orbitals

In the light of the above statements, choose the correct answer from the options given below

Options

  1. AA is false but R is true
  2. BBoth A and R are true and R is the correct explanation of A
  3. CA is true but R is false
  4. DBoth A and R are true but R is NOT the correct explanation of A

Correct answer

B. Both A and R are true and R is the correct explanation of A

Step-by-step solution

The distance between the nucleus and 5f orbital is more than the distance between the nucleus and 4f orbital. Hence the hold of nucleus on valence electron decrease in 5f orbital. 5f orbital not buried as 4f oribitals so electron present in 5f orbital experience less nuclear attraction than electron present in 4f orbital. Hence electrons of 5f orbital can take part in bonding to far great extent.

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