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JEE Main 202310 AprilEvening Shift
Exam
JEE Main
Year
2023
Date
10 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Structure of Atom

JEE Main 2023 · 10 April · Evening Shift · Chemistry · Structure of Atom

The electron in the n ^ th orbit of Li ^ 2 + is excited to ( n + 1...

The electron in the n ^ th orbit of Li ^ 2 + is excited to ( n + 1 ) orbit using the radiation of energy 1 . 47 × 10 ^

The electron in the nth{n}^{th} orbit of Li2+{Li}^{2 +} is excited to (n+1)( n + 1 ) orbit using the radiation of energy 1.47×10−17J1 . 47 \times {10}^{- 17}J (as shown in the diagram). The value of nn is ___________

Given : RH=2.18×10−18J{R}_{H} = 2 . 18 \times {10}^{- 18}J

Correct answer

0

Step-by-step solution

The difference energy between two energy levels is

∆E=2.18×10−18[1n12−1n22]J∆ E = 2 . 18 \times {10}^{- 18}\left[1{n}_{1}^{2} - 1{n}_{2}^{2}\right]J

1.47×10−17=2.18×10−18×(9)(1(n)2−1(n+1)2)1 . 47 \times {10}^{- 17} = 2 . 18 \times {10}^{- 18} \times ( 9 ) \left(\dfrac{1}{( n{)}^{2}} - \dfrac{1}{( n + 1{)}^{2}}\right)

0.749=1n2−1(n+1)20 . 749 = \dfrac{1}{{n}^{2}} - \dfrac{1}{( n + 1{)}^{2}}

n=1n = 1

Hence, the transition is taking place between 1→21\overset{}{\to}2, and it comes under Lymann series.

If we take 0.749≃0.75=340 . 749 ≃ 0 . 75 = \dfrac{3}{4}

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