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JEE Main 202331 JanuaryEvening Shift
Exam
JEE Main
Year
2023
Date
31 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Structure of Atom

JEE Main 2023 · 31 January · Evening Shift · Chemistry · Structure of Atom

Arrange the following orbitals in decreasing order of energy. A. n...

Arrange the following orbitals in decreasing order of energy.

A. n=3,l=0,m=0n = 3, l = 0, m = 0
B. n=4,l=0,m=0n = 4, l = 0, m = 0
C. n=3,l=1,m=0n = 3, l = 1, m = 0
D. n=3,l=2,m=1n = 3, l = 2, m = 1

The correct option for the order is:

Options

  1. AD > B > C > A
  2. BB > D > C > A
  3. CA > C > B > D
  4. DD > B > A > C

Correct answer

A. D > B > C > A

Step-by-step solution

In multi-electronic species, energy is decided on the basis of (n+ln + l) rule.

3s=3+0+0=33s = 3 + 0 + 0 = 3

4s=4+0+0=44s = 4 + 0 + 0 = 4

3p=3+1+0=43p = 3 + 1 + 0 = 4

3d=3+2+1=63d = 3 + 2 + 1 = 6

For 4s and 3p, an orbital with a higher value of n has higher energy.

So increasing the order of energy is 3d>4s>3p>3s3d > 4s > 3p > 3s.

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