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JEE Main 202325 JanuaryMorning Shift
Exam
JEE Main
Year
2023
Date
25 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Structure of Atom

JEE Main 2023 · 25 January · Morning Shift · Chemistry · Structure of Atom

The radius of the 2 nd orbit of Li ^ 2 + is x . The expected radius...

The radius of the 2nd orbit of Li2+{Li}^{2 +} is xx. The expected radius of the 3rd orbit of Be3+{Be}^{3 +} is

Options

  1. A94x\dfrac{9}{4}x
  2. B49x\dfrac{4}{9}x
  3. C2716x\dfrac{27}{16}x
  4. D1627x\dfrac{16}{27}x

Correct answer

C. 2716x\dfrac{27}{16}x

Step-by-step solution

Radius of orbit (r)=0.529×n2Z( r ) = 0 . 529 \times \dfrac{{n}^{2}}{Z}

Where, n = principal quantum number of orbit

Z = Atomic number

(rLi2+)n=2=0.529×(2)23=x−−−−−(1)( r{Li}^{2 +}{)}_{n = 2} = 0 . 529 \times \dfrac{( 2{)}^{2}}{3} = x - - - - - ( 1 )

(rBe3+)n=3=0.529×(3)24−−−−−(2){\left(r{Be}^{3 +}\right)}_{n = 3} = 0 . 529 \times \dfrac{( 3{)}^{2}}{4} - - - - - ( 2 )

Divide equation (1) by equation (2)

(rLi2+)n=2(rBe3+)n=3=0.529×(2)230.529×(3)24\dfrac{{\left(r{Li}^{2 +}\right)}_{n = 2}}{{\left(r{Be}^{3 +}\right)}_{n = 3}} = \dfrac{0 . 529 \times \dfrac{( 2{)}^{2}}{3}}{0 . 529 \times \dfrac{( 3{)}^{2}}{4}}

⇒x(rBe3+)n=3=1627⇒ \dfrac{x}{( r{Be}^{3 +}{)}_{n = 3}} = \dfrac{16}{27}

∴(rBe3+)n=3=27x16∴ {\left(r{Be}^{3 +}\right)}_{n = 3} = \dfrac{27x}{16}

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