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JEE Main 202227 JulyMorning Shift
Exam
JEE Main
Year
2022
Date
27 July
Shift
Morning Shift
Subject
Chemistry
Chapter
Structure of Atom

JEE Main 2022 · 27 July · Morning Shift · Chemistry · Structure of Atom

Given below are two statements. One is labelled as Assertion A and...

Given below are two statements. One is labelled as Assertion AA and the other is labelled as Reason RR.

Assertion AA : Energy of 2s2s orbital of hydrogen atom is greater than that of 2s2s orbital of lithium.

Reason RR : Energies of the orbitals in the same subshell decrease with increase in the atomic number.

In the light of the above statements, choose the correct answer from the options given below.

Options

  1. ABoth AA and RR are true and RR is the correct explanation of AA.
  2. BBoth AA and RR are true but RR is NOT the correct explanation of AA.
  3. CAA is true but RR is false.
  4. DAA is false but RR is true.

Correct answer

A. Both AA and RR are true and RR is the correct explanation of AA.

Step-by-step solution

As given in question (A) and (R) both are correct and (R) is the correct explanation of (A)

We know that for the electron in the same orbital, attraction is more for a larger atomic number. An increase of attraction decreases the energy of the orbital and the electron present in it.

Hence, the given reason in question is correct that energies of the orbitals in the same subshell decreases with an increase in the atomic number.

Taking into account the given elements, 2s−2s -orbital (energy level)ofHof H atom will have greater energy than that of 2s−2s -orbital of Li−Li - atom.

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