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JEE Main 202225 JulyMorning Shift
Exam
JEE Main
Year
2022
Date
25 July
Shift
Morning Shift
Subject
Chemistry
Chapter
Structure of Atom

JEE Main 2022 · 25 July · Morning Shift · Chemistry · Structure of Atom

Which of the following sets of quantum numbers is not allowed?

Which of the following sets of quantum numbers is not allowed?

Options

  1. An=3,l=2,ml=0,s=+12n = 3, l = 2, {m}_{l} = 0, s = + \dfrac{1}{2}
  2. Bn=3,l=2,ml=−2,s=+12n = 3, l = 2, {m}_{l} = - 2, s = + \dfrac{1}{2}
  3. Cn=3,l=3,ml=−3,s=−12n = 3, l = 3, {m}_{l} = - 3, s = - \dfrac{1}{2}
  4. Dn=3,l=0,ml=0,s=−12n = 3, l = 0, {m}_{l} = 0, s = - \dfrac{1}{2}

Correct answer

C. n=3,l=3,ml=−3,s=−12n = 3, l = 3, {m}_{l} = - 3, s = - \dfrac{1}{2}

Step-by-step solution

The possible values of principal quantum number ′n′' n ' can be any positive integer.

For a particular value of ′n′' n ', the possible values of azimuthal quantum number is from 0to(n−1).</p><p>Thus,for0 to \left(n - 1\right).</p><p>Thus, forn = 3,thepossible, the possible' l 'valuesarevalues are0, 1, 2.</p><p>Thepossiblevaluesofmagneticquantumnumber.</p><p>The possible values of magnetic quantum number' m 'isfromis from' - l ' to ' + l '.</p><p>Thus,for.</p><p>Thus, forl = 2,thepossiblevaluesof, the possible values of' m 'areare- 2, - 1, 0, + 1, + 2.</p><p>Thepossiblevaluesofspinquantumnumber.</p><p>The possible values of spin quantum number' s 'isis- 12\dfrac{1}{2} and + 12.</p><p>InoptionC.</p><p>\dfrac{1}{2}.</p><p>In option C.</p><p>⇒ l = 3,notpossiblefornot possible forn = 3</p></blockquote></p></blockquote>

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