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JEE Main 202127 AugustMorning Shift
Exam
JEE Main
Year
2021
Date
27 August
Shift
Morning Shift
Subject
Chemistry
Chapter
Structure of Atom

JEE Main 2021 · 27 August · Morning Shift · Chemistry · Structure of Atom

1kg of 0 . 75 molal aqueous solution of sucrose can be cooled up to...

1kg1kg of 0.750 . 75 molal aqueous solution of sucrose can be cooled up to −4°C- 4 ° C before freezing. The amount of ice (in gg) that will be separated out is ___________. (Nearest integer) [Given : Kf(H2O)=1.86Kkgmol−1{K}_{f}\left({H}_{2}O\right) = 1 . 86Kkg{mol}^{- 1}]

Correct answer

0

Step-by-step solution

Let mass of water initially present =xg= xg

Mass of sucrose =(1000−x)g= ( 1000 - x ) g

Number of moles sucrose =1000−x342= \dfrac{1000 - x}{342}

Molality \left(M\right) = \dfrac{\dfrac{1000 - x}{342}}{x / 1000} = 0 . 75</p><p></p><p>2565 . 5x = {10}^{6} - 1000x</p><p></p><p>x = 795 . 86g</p><p>no.ofmolesofsucrose</p><p>no. of moles of sucrose= 0 . 5969</p><p></p><p>{\Delta T}_{f} = {ik}_{f}m</p><p></p><p>4 = 1 \times 1 . 86 \times \dfrac{0 . 5969}{( 795 . 86 - a ) g} \times 1000</p><p>Iceseparated</p><p>Ice separated= 518 . 3g$

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