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JEE Main 20203 SeptemberEvening Shift
Exam
JEE Main
Year
2020
Date
3 September
Shift
Evening Shift
Subject
Chemistry
Chapter
Structure of Atom

JEE Main 2020 · 3 September · Evening Shift · Chemistry · Structure of Atom

Consider the hypothetical situation where the azimuthal quantum...

Consider the hypothetical situation where the azimuthal quantum number, ll, takes values 0,1,2,……..n+10, 1, 2, \ldots \ldots . . n + 1. Where n is the principal quantum number. Then, the element with atomic number:

Options

  1. A9 is the first alkali metal
  2. B13 has a half-filled valence subshell
  3. C8 is the first noble gas
  4. D6 has a 2p-valence subshell

Correct answer

B. 13 has a half-filled valence subshell

Step-by-step solution

For n=1n = 1 value of l=0,1,2l = 0, 1, 2

For n=2n = 2 value of l=0,1,2,3l = 0, 1, 2, 3

So, according to n+ln + l rule the filling order of subshells will be :

1s1p2s1d2p3s2d3p4s.....1s1p2s1d2p3s2d3p4s . . . . .

(1) 1st{1}^{st} alkali metal will have configuration 1s21p61{s}^{2}1{p}^{6} so atomic number will be 88.

(2) 1st{1}^{st} alkali metal will have electronic configuration ⇒1s1⇒(Z=1)⇒ 1{s}^{1} ⇒ \left(Z = 1\right)

(3) Electronic configuration of C(Z=6)⇒1s21p4C\left(Z = 6\right) ⇒ 1{s}^{2}1{p}^{4}

(4) Z=13Z = 13, Electronic configuration =1s21p62s21d3= 1{s}^{2}1{p}^{6}2{s}^{2}1{d}^{3}

So it will not have half-filled electronic configuration.

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