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JIPMER2007ChemistryClassification of Elements and Periodicity in Properties

What is the correct relationship between the pHs of isomolar solutions of sodium oxide ( pH ₁ ) , sodium sulphide ( pH ₂ ) , sodium selenide ( pH ₃ ) and sodium telluride ( pH ₄ ) ?

Options

  1. ApH ₁ pH ₂ pH ₃ pH ₄
  2. BpH ₁ pH ₂ pH ₃ pH ₄
  3. CpH ₁ pH ₂ pH ₃ pH ₄
  4. DpH ₁ pH ₂ pH ₃ pH ₄

Correct answer

D. pH ₁ pH ₂ pH ₃ pH ₄

Step-by-step solution

The correct order of pH of isomolar solution in sodium oxide ( pH ₁ ) , sodium sulphide ( pH ₂ ) , sodium selenide ( pH ₃ ) and sodium telluride ( pH ₄ ) is pH ₁ pH ₂ pH ₃ pH ₄ because in aqueous solution, they are hydrolysed as follows. Na ₂ O +2 H ₂ O Base 2 NaOH + H ₂ O Na ₂ ~S +2 H ₂ O Strong base 2 NaOH + Weak acid H ₂ ~S Na ₂ Se +2 H ₂ O Strong base 2 NaOH + gathered H ₂ Se Weak acid gathered Na ₂ Te +2 H ₂ O Strong base 2 NaOH + gathered H ₂ Te Weak acid gathered Order of acidic strength H ₂ Te H ₂ Se H ₂ ~S

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