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JIPMER 2018
Exam
JIPMER
Year
2018
Subject
Chemistry
Chapter
Electrochemistry

JIPMER 2018 · Chemistry · Electrochemistry

The product of electrolysis of aqueous NaCl solution on anode and...

The product of electrolysis of aqueous NaCl solution on anode and cathode respectively is

Options

  1. AH2\mathrm{H}_2 and Cl2\mathrm{Cl}_2
  2. BCl2\mathrm{Cl}_2 and H2\mathrm{H}_2
  3. CNa and Cl2\mathrm{Cl}_2
  4. DNa and O2\mathrm{O}_2

Correct answer

A. H2\mathrm{H}_2 and Cl2\mathrm{Cl}_2

Step-by-step solution

In case of electrolysis of aqueous NaCl , oxidation and reduction reaction occurs at anode and cathode respectively as shown below: At cathode H2O(l)+e−⟶12H2( g)+OH−(aq)\mathrm{H}_2 \mathrm{O}(\mathrm{l})+\mathrm{e}^{-} \longrightarrow \frac{1}{2} \mathrm{H}_2(\mathrm{~g})+\mathrm{OH}^{-}(\mathrm{aq}) At anode Cl−(aq)⟶12Cl2( g)+e−\mathrm{Cl}^{-}(\mathrm{aq}) \longrightarrow \frac{1}{2} \mathrm{Cl}_2(\mathrm{~g})+\mathrm{e}^{-} Net cell reaction is as follows NaCl(aq)+H2O(l)⟶Na+(aq)\mathrm{NaCl}(\mathrm{aq})+\mathrm{H}_2 \mathrm{O}(\mathrm{l}) \longrightarrow \mathrm{Na}^{+}(\mathrm{aq}) +OH−(aq)+12H2( g)+12Cl2( g)+\mathrm{OH}^{-}(\mathrm{aq})+\frac{1}{2} \mathrm{H}_2(\mathrm{~g})+\frac{1}{2} \mathrm{Cl}_2(\mathrm{~g}) Thus, the product of electrolysis of NaCl solution on cathode and anode is H2\mathrm{H}_2 and Cl2\mathrm{Cl}_2.
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