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JIPMER 2013
Exam
JIPMER
Year
2013
Subject
Chemistry
Chapter
Electrochemistry

JIPMER 2013 · Chemistry · Electrochemistry

Which of the following statement is correct?

Which of the following statement is correct?

Options

  1. AEcell E_{\text{cell }} and ΔtG\Delta_t G of cell reaction both are extensive properties.
  2. BEcell E_{\text{cell }} and ΔrG\Delta_r G of cell reaction both are intensive properties.
  3. CEcell E_{\text{cell }} in the intensive property while ΔrG\Delta_r G of cell reaction is an extensive property.
  4. DEcell E_{\text{cell }} is an extensive property while ΔrG\Delta_r G of cell reaction is an intensive property.

Correct answer

C. Ecell E_{\text{cell }} in the intensive property while ΔrG\Delta_r G of cell reaction is an extensive property.

Step-by-step solution

Ecell E_{\text{cell }} is intensive while ΔrG\Delta_r G is extensive. (In the relation, ΔG=−nFE,E\Delta G=-n F E, E depends only on the nature of the cell reaction so it is intensive whereas value of ΔG\Delta G depends upon the value of nn. So it is extensive.)
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