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JIPMER 2015
Exam
JIPMER
Year
2015
Subject
Chemistry
Chapter
Electrochemistry

JIPMER 2015 · Chemistry · Electrochemistry

Point out the incorrect reaction from the following.

Point out the incorrect reaction from the following.Point out the incorrect reaction from the following.

Options

  1. A2Na2CrO4+H+⟶Na2Cr2O7+2Na++H2O2 \mathrm{Na}_2 \mathrm{CrO}_4+\mathrm{H}^{+} \longrightarrow \mathrm{Na}_2 \mathrm{Cr}_2 \mathrm{O}_7+2 \mathrm{Na}^{+}+\mathrm{H}_2 \mathrm{O}
  2. B4MnO2+4KOH+O2⟶4KMnO4+2H2O4 \mathrm{MnO}_2+4 \mathrm{KOH}+\mathrm{O}_2 \longrightarrow 4 \mathrm{KMnO}_4+2 \mathrm{H}_2 \mathrm{O}
  3. C2MnO4−+5C2O42−+16H+⟶2Mn2++10CO2+8H2O\begin{aligned} 2 \mathrm{MnO}_4^{-}+5 \mathrm{C}_2 \mathrm{O}_4^{2-}+16 \mathrm{H}^{+} \longrightarrow \\ 2 \mathrm{Mn}^{2+}+10 \mathrm{CO}_2+8 \mathrm{H}_2 \mathrm{O}\end{aligned}
  4. DThe compound which shows metamerism is:

Correct answer

B. 4MnO2+4KOH+O2⟶4KMnO4+2H2O4 \mathrm{MnO}_2+4 \mathrm{KOH}+\mathrm{O}_2 \longrightarrow 4 \mathrm{KMnO}_4+2 \mathrm{H}_2 \mathrm{O}

Step-by-step solution

Pyrolusite ore, MnO2\mathrm{MnO}_2 on fusion with KOH in presence of air forms potassium manganate, K2MnO4\mathrm{K}_2 \mathrm{MnO}_4 2MnO2+4KOH+O2⟶2 K2MnO4+2H2O2 \mathrm{MnO}_2+4 \mathrm{KOH}+\mathrm{O}_2 \longrightarrow 2 \mathrm{~K}_2 \mathrm{MnO}_4+2 \mathrm{H}_2 \mathrm{O}
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