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JIPMER 2019
Exam
JIPMER
Year
2019
Subject
Chemistry
Chapter
Haloalkanes and Haloarenes

JIPMER 2019 · Chemistry · Haloalkanes and Haloarenes

CH_3-CH_2-CH_2-Br Alc. KOH Final product is

CH3−CH2−CH2−Br→ Alc. KOH\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{CH}_2-\mathrm{Br} \xrightarrow{\text{ Alc. } \mathrm{KOH}} Final product is

Options

  1. Apropene
  2. Bpropanol
  3. Ccyclopropane
  4. Dpropane-1, 2-diol

Correct answer

A. propene

Step-by-step solution

When haloalkane containing β\beta-hydrogen atom is heated with alc. KOH solution, then alkene is formed CH3CH2CH2Br→ alc. KOHCH3−CH Propene =CH2\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{Br} \xrightarrow{\text{ alc. } \mathrm{KOH}} \mathrm{CH}_3 - \underset{\text{ Propene }}{\mathrm{CH}}=\mathrm{CH}_2 In this reaction, hydrogen is elimated from β\beta-carbon and the halogen is lost from α\alpha-carbon atom. As a result, an alkene is formed as a product. Due to the involvement of elimination of β\beta -hydrogen atom, the process is often called β\beta-elimination.
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