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JIPMER2007ChemistryHydrocarbons

Electrolytic reduction of nitrobenzene in weakly acidic medium gives

Options

  1. Aaniline
  2. Bnitrosobenzene
  3. CN-phenylhydroxylamine
  4. Dp-hydroxyaniline

Correct answer

C. N-phenylhydroxylamine

Step-by-step solution

Electrolytic reduction of nitrobenzene in a weakly acidic medium gives aniline but in a strongly acidic medium, it gives p-aminophenol through the acidcatalyzed rearrangement of the initially formed phenylhydroxylamine.

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