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AIIMS2019ChemistryElectrochemistry

Calculate emf of the following cell at 25^ C if value of E_ cell ^ is 4 ~V (Given R T / F 10=0.06 ) : M |M_ (0.01 M ) ²⁺ | |M_ (0.0001 M ) ²⁺ | M

Options

  1. A3.94 ~V
  2. B4.06 ~V
  3. C2.03 ~V
  4. D8.18 ~V

Correct answer

A. 3.94 ~V

Step-by-step solution

aligned & E_ cell =E_ cell ^ - R T 2 F 0.01 0.0001 & =4- R T 2 F 10⁻² 10⁻⁴ =4- R T 2 F 10^2 & =4- R T F 10=4-0.06=3.94 ~V aligned

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