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AIIMS2010ChemistryElectrochemistry

For the electrochemical cell, M |M⁺ | X⁻ | X , E^ (M⁺ M )=0.44 ~V and E^ (X X⁻ )=0.33 ~V . From this data one can deduce that

Options

  1. AM+X M⁺+X⁻ is the spontaneous reaction
  2. BM⁺+X⁻ M+X is the spontaneous reaction
  3. CE_ cell =0.77 ~V
  4. DE_ cell =-0.77 ~V

Correct answer

B. M⁺+X⁻ M+X is the spontaneous reaction

Step-by-step solution

M⁺+X⁻ M+X is spontaneous because for the cell represented by M |M⁺ | X | X , the value of E^ is positive i.e. (0.44-0.33) V =0.11 ~V .

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