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AIIMS2016ChemistryElectrochemistry

A conductivity cell has a cell constant of 0.5 ~cm ⁻¹ . This cell when filled with 0.01 M NaCl solution has a resistance of 384 ohms at 25^ C . Calculate the equivalent conductance of the given solution.

Options

  1. A130.2 ⁻¹ ~cm ^2( ~g eq )⁻¹
  2. B137.4 ⁻¹ ~cm ^2( ~g eq )⁻¹
  3. C154.6 ⁻¹ ~cm ^2( ~g eq )⁻¹
  4. D169.2 ⁻¹ ~cm ^2( ~g eq )⁻¹

Correct answer

A. 130.2 ⁻¹ ~cm ^2( ~g eq )⁻¹

Step-by-step solution

aligned & Equivalent conductance, _ e q = 1000 Normality & where, (Specific conductance) =C l a & = 1 R l a = 1 384 0.5 & =1.302 10⁻³ ohm ⁻¹ ~cm ⁻¹ & _ e q = 1.302 10⁻³ 1000 0.01 & =130.2 ohm ⁻¹ ~cm ^2( ~g eq )⁻¹ aligned

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