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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

The molar conductivity of a 0.02 M solution of propanoic acid is...

The molar conductivity of a 0.02 M0.02 \text{ M} solution of propanoic acid is 31.2 S cm2 mol−131.2 \text{ S cm}^2 \text{ mol}^{-1}. What is the percentage dissociation of the acid in this solution?

[Given: Limiting molar conductivities of H+\text{H}^+ and C2H5COO−\text{C}_2\text{H}_5\text{COO}^- are 349.6 S cm2 mol−1349.6 \text{ S cm}^2 \text{ mol}^{-1} and 40.4 S cm2 mol−140.4 \text{ S cm}^2 \text{ mol}^{-1} respectively]

Options

  1. A0.08%0.08\%
  2. B4.0%4.0\%
  3. C8.0%8.0\%
  4. D12.5%12.5\%

Correct answer

C. 8.0%8.0\%

Step-by-step solution

The limiting molar conductivity of propanoic acid is given by Kohlrausch's law:

Λm∘(C2H5COOH)=λ∘(H+)+λ∘(C2H5COO−)\Lambda_{m}^{\circ}(\text{C}_{2}\text{H}_{5}\text{COOH}) = \lambda^{\circ}(\text{H}^{+}) + \lambda^{\circ}(\text{C}_{2}\text{H}_{5}\text{COO}^{-})

Substituting the given values:

Λm∘=349.6+40.4=390.0 S cm2 mol−1\Lambda_{m}^{\circ} = 349.6 + 40.4 = 390.0 \text{ S cm}^{2} \text{ mol}^{-1}

The degree of dissociation α\alpha is the ratio of molar conductivity at a given concentration to the limiting molar conductivity:

α=ΛmΛm∘\alpha = \dfrac{\Lambda_{m}}{\Lambda_{m}^{\circ}}

α=31.2390.0=0.08\alpha = \dfrac{31.2}{390.0} = 0.08

The percentage dissociation is:

α×100=0.08×100=8.0%\alpha \times 100 = 0.08 \times 100 = 8.0\%

Answer: 8.0%8.0\%
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