NEET 2026
- Exam
- NEET
- Year
- 2026
- Subject
- Chemistry
- Chapter
- Chapter
NEET 2026 · Chemistry · Chapter
An organic compound X ( C_6H_7N ) on treatment with NaNO_2 and...
An organic compound () on treatment with and dilute at forms an intermediate . The intermediate is unstable in the dry state but can be maintained in a cold aqueous solution. When is reacted with ethanol, it yields a hydrocarbon , along with the evolution of nitrogen gas and the formation of ethanal.
Which of the following statements is correct regarding this reaction sequence?
Which of the following statements is correct regarding this reaction sequence?
Options
- ACompound is a primary aliphatic amine, and is an aliphatic diazonium salt.
- BThe formation of from is a nucleophilic substitution reaction where ethanol acts as a nucleophile.
- CThe conversion of to is a redox process in which ethanol acts as a reducing agent.
- DIntermediate is highly stable at room temperature due to resonance stabilization of the diazonium ion.
Correct answer
C. The conversion of to is a redox process in which ethanol acts as a reducing agent.
Step-by-step solution
Compound with the molecular formula is aniline (), which is a primary aromatic amine.
When aniline is treated with and dilute at , it undergoes diazotization to form benzenediazonium chloride (), which is the intermediate .
Benzenediazonium chloride reacts with ethanol () to yield benzene (), which is the hydrocarbon , along with nitrogen gas and ethanal (). The chemical equation is:
In this reaction, the diazonium salt is reduced to benzene, and ethanol is oxidized to ethanal. Therefore, ethanol acts as a reducing agent, making the conversion of to a redox process.
Option (A) is incorrect because is an aromatic amine, not aliphatic.
Option (B) is incorrect because the reaction is a reduction, not a nucleophilic substitution.
Option (D) is incorrect because benzenediazonium chloride is unstable at room temperature and must be kept cold ().
Answer: The conversion of to is a redox process in which ethanol acts as a reducing agent.
When aniline is treated with and dilute at , it undergoes diazotization to form benzenediazonium chloride (), which is the intermediate .
Benzenediazonium chloride reacts with ethanol () to yield benzene (), which is the hydrocarbon , along with nitrogen gas and ethanal (). The chemical equation is:
In this reaction, the diazonium salt is reduced to benzene, and ethanol is oxidized to ethanal. Therefore, ethanol acts as a reducing agent, making the conversion of to a redox process.
Option (A) is incorrect because is an aromatic amine, not aliphatic.
Option (B) is incorrect because the reaction is a reduction, not a nucleophilic substitution.
Option (D) is incorrect because benzenediazonium chloride is unstable at room temperature and must be kept cold ().
Answer: The conversion of to is a redox process in which ethanol acts as a reducing agent.