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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

For the reaction CO(g) + H_2O(g) leftharpoons CO_2(g) + H_2(g) ,...

For the reaction CO(g)+H2O(g)⇌CO2(g)+H2(g)\text{CO(g)} + \text{H}_2\text{O(g)} \rightleftharpoons \text{CO}_2\text{(g)} + \text{H}_2\text{(g)}, the equilibrium constant KcK_c is 4.04.0 at a specific temperature. If a reaction mixture contains 0.1 M0.1\text{ M} of CO\text{CO}, 0.1 M0.1\text{ M} of H2O\text{H}_2\text{O}, 0.4 M0.4\text{ M} of CO2\text{CO}_2, and 0.4 M0.4\text{ M} of H2\text{H}_2 at a given instant, predict the behavior of the system.

Options

  1. AThe reaction will proceed in the forward direction, consuming CO\text{CO} and H2O\text{H}_2\text{O}.
  2. BThe reaction will proceed in the reverse direction, consuming CO2\text{CO}_2 and H2\text{H}_2.
  3. CThe equilibrium constant KcK_c will decrease to match the reaction quotient.
  4. DThe system is already at equilibrium, so no net change will occur.

Correct answer

B. The reaction will proceed in the reverse direction, consuming CO2\text{CO}_2 and H2\text{H}_2.

Step-by-step solution

The reaction quotient QcQ_c is calculated using the given concentrations of the species at the given instant:

Qc=[CO2][H2][CO][H2O]Q_c = \dfrac{[\text{CO}_2][\text{H}_2]}{[\text{CO}][\text{H}_2\text{O}]}

Substituting the given values:

Qc=0.4×0.40.1×0.1=0.160.01=16Q_c = \dfrac{0.4 \times 0.4}{0.1 \times 0.1} = \dfrac{0.16}{0.01} = 16

The equilibrium constant is given as Kc=4.0K_c = 4.0.

Comparing QcQ_c and KcK_c, we find that Qc>KcQ_c > K_c. Since the reaction quotient is greater than the equilibrium constant, the system is not at equilibrium. To reach equilibrium, the reaction will proceed in the reverse direction, consuming the products CO2\text{CO}_2 and H2\text{H}_2 to form more reactants CO\text{CO} and H2O\text{H}_2\text{O}.

Answer: The reaction will proceed in the reverse direction, consuming CO2\text{CO}_2 and H2\text{H}_2.
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