NEET 2026
- Exam
- NEET
- Year
- 2026
- Subject
- Chemistry
- Chapter
- Chapter
NEET 2026 · Chemistry · Chapter
Identify the major products A and B formed in the following...
Identify the major products A and B formed in the following reaction sequence.
Options
- AA = 3-Chloro-2-methylpentane ; B = 2-Methylpent-2-ene
- BA = 2-Chloro-3-methylpentane ; B = 3-Methylpent-2-ene
- CA = 3-Chloro-2-methylpentane ; B = 4-Methylpent-2-ene
- DA = 2-Chloro-2-methylpentane ; B = 2-Methylpent-2-ene
Correct answer
A. A = 3-Chloro-2-methylpentane ; B = 2-Methylpent-2-ene
Step-by-step solution
The given starting material is 2-methylpentan-3-ol, with the structure .
Step 1: Reaction with
Thionyl chloride () converts alcohols into alkyl chlorides. This reaction proceeds without the formation of a free carbocation, meaning no rearrangement takes place. The group is directly replaced by a atom.
Product A is , which is named 3-chloro-2-methylpentane.
Step 2: Reaction with alc.
Alcoholic with heat brings about dehydrohalogenation (an E2 elimination reaction). The removal of can occur in two possible directions from 3-chloro-2-methylpentane:
1. Elimination between C2 and C3 yields (2-methylpent-2-ene). This is a trisubstituted alkene with 8 -hydrogens.
2. Elimination between C3 and C4 yields (4-methylpent-2-ene). This is a disubstituted alkene with 4 -hydrogens.
According to Zaitsev's rule, the more substituted and more stable alkene is formed as the major product. Thus, the major product B is 2-methylpent-2-ene.
Therefore, A = 3-Chloro-2-methylpentane and B = 2-Methylpent-2-ene.
Answer: A = 3-Chloro-2-methylpentane ; B = 2-Methylpent-2-ene
Step 1: Reaction with
Thionyl chloride () converts alcohols into alkyl chlorides. This reaction proceeds without the formation of a free carbocation, meaning no rearrangement takes place. The group is directly replaced by a atom.
Product A is , which is named 3-chloro-2-methylpentane.
Step 2: Reaction with alc.
Alcoholic with heat brings about dehydrohalogenation (an E2 elimination reaction). The removal of can occur in two possible directions from 3-chloro-2-methylpentane:
1. Elimination between C2 and C3 yields (2-methylpent-2-ene). This is a trisubstituted alkene with 8 -hydrogens.
2. Elimination between C3 and C4 yields (4-methylpent-2-ene). This is a disubstituted alkene with 4 -hydrogens.
According to Zaitsev's rule, the more substituted and more stable alkene is formed as the major product. Thus, the major product B is 2-methylpent-2-ene.
Therefore, A = 3-Chloro-2-methylpentane and B = 2-Methylpent-2-ene.
Answer: A = 3-Chloro-2-methylpentane ; B = 2-Methylpent-2-ene