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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

Assertion : p -Methoxyphenol is a weaker acid than m...

Assertion : pp-Methoxyphenol is a weaker acid than mm-methoxyphenol.
Reason : The −OCH3-OCH_3 group exerts a +I+I effect which destabilizes the conjugate base.

Options

  1. ABoth Assertion and Reason are true and Reason is the correct explanation of Assertion.
  2. BBoth Assertion and Reason are true but Reason is not the correct explanation of Assertion.
  3. CAssertion is true but Reason is false.
  4. DBoth Assertion and Reason are false.

Correct answer

C. Assertion is true but Reason is false.

Step-by-step solution

The −OCH3-OCH_3 group exerts a −I-I effect and a +R+R effect.

In pp-methoxyphenol, the +R+R effect of the −OCH3-OCH_3 group is dominant over its −I-I effect. This increases the electron density on the phenoxide ion, destabilizing the conjugate base and making it a weaker acid.

In mm-methoxyphenol, the +R+R effect does not operate at the meta position. Only the −I-I effect operates, which stabilizes the phenoxide ion, making it a stronger acid.

Thus, pp-methoxyphenol is a weaker acid than mm-methoxyphenol. The Assertion is true.

The Reason states that the −OCH3-OCH_3 group exerts a +I+I effect, which is incorrect since oxygen is more electronegative than carbon and exerts a −I-I effect. Therefore, the Reason is false.

Answer: Assertion is true but Reason is false.
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