NEET 2026
- Exam
- NEET
- Year
- 2026
- Subject
- Chemistry
- Chapter
- Chapter
NEET 2026 · Chemistry · Chapter
Assertion : p -Methoxyphenol is a weaker acid than m...
Assertion : -Methoxyphenol is a weaker acid than -methoxyphenol.
Reason : The group exerts a effect which destabilizes the conjugate base.
Reason : The group exerts a effect which destabilizes the conjugate base.
Options
- ABoth Assertion and Reason are true and Reason is the correct explanation of Assertion.
- BBoth Assertion and Reason are true but Reason is not the correct explanation of Assertion.
- CAssertion is true but Reason is false.
- DBoth Assertion and Reason are false.
Correct answer
C. Assertion is true but Reason is false.
Step-by-step solution
The group exerts a effect and a effect.
In -methoxyphenol, the effect of the group is dominant over its effect. This increases the electron density on the phenoxide ion, destabilizing the conjugate base and making it a weaker acid.
In -methoxyphenol, the effect does not operate at the meta position. Only the effect operates, which stabilizes the phenoxide ion, making it a stronger acid.
Thus, -methoxyphenol is a weaker acid than -methoxyphenol. The Assertion is true.
The Reason states that the group exerts a effect, which is incorrect since oxygen is more electronegative than carbon and exerts a effect. Therefore, the Reason is false.
Answer: Assertion is true but Reason is false.
In -methoxyphenol, the effect of the group is dominant over its effect. This increases the electron density on the phenoxide ion, destabilizing the conjugate base and making it a weaker acid.
In -methoxyphenol, the effect does not operate at the meta position. Only the effect operates, which stabilizes the phenoxide ion, making it a stronger acid.
Thus, -methoxyphenol is a weaker acid than -methoxyphenol. The Assertion is true.
The Reason states that the group exerts a effect, which is incorrect since oxygen is more electronegative than carbon and exerts a effect. Therefore, the Reason is false.
Answer: Assertion is true but Reason is false.