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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

Identify the final major product [S] obtained in the following...

Identify the final major product [S] obtained in the following sequence of reactions:

Identify the final major product [S] obtained in the following sequence of reactions: (i) LiAlH_4 , (ii) H_3O^+ [P] [Δ]→(i) LiAlH4, (ii) H3O+[P]→Δconc. H2SO4[Q]→(i) B2H6/THF, (ii) H2O2/OH−[R]→PCC[S]\xrightarrow{\text{(i) } LiAlH_4 \text{, (ii) } H_3O^+} [\text{P}] \xrightarrow[\Delta]{\text{conc. } H_2SO_4} [\text{Q}] \xrightarrow{\text{(i) } B_2H_6 \text{/THF, (ii) } H_2O_2/OH^-} [\text{R}] \xrightarrow{PCC} [\text{S}]

Options

  1. A1-Phenylethanone
  2. B2-Phenylethanal
  3. CPhenylacetic acid
  4. D2-Phenylethanol

Correct answer

B. 2-Phenylethanal

Step-by-step solution

The starting material is acetophenone (C6H5−CO−CH3C_6H_5-CO-CH_3).

Reaction with LiAlH4LiAlH_4 followed by acidic workup reduces the ketone to a secondary alcohol. Thus, [P][P] is 1-phenylethanol (C6H5−CH(OH)−CH3C_6H_5-CH(OH)-CH_3).

Heating [P][P] with concentrated H2SO4H_2SO_4 causes dehydration, forming an alkene. The major product is styrene (C6H5−CH=CH2C_6H_5-CH=CH_2) due to conjugation with the benzene ring. Thus, [Q][Q] is styrene.

Hydroboration-oxidation of [Q][Q] using B2H6B_2H_6/THF followed by H2O2/OH−H_2O_2/OH^- leads to anti-Markovnikov hydration of the alkene. This yields a primary alcohol, 2-phenylethanol (C6H5−CH2−CH2−OHC_6H_5-CH_2-CH_2-OH). Thus, [R][R] is 2-phenylethanol.

Finally, oxidation of [R][R] with Pyridinium chlorochromate (PCC) selectively oxidizes the primary alcohol to an aldehyde without over-oxidation. The product is 2-phenylethanal (C6H5−CH2−CHOC_6H_5-CH_2-CHO).

Therefore, the final major product [S][S] is 2-phenylethanal.

Answer: 2-Phenylethanal
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