NEET 2026
- Exam
- NEET
- Year
- 2026
- Subject
- Chemistry
- Chapter
- Chapter
NEET 2026 · Chemistry · Chapter
The carbon-carbon single bond length in propene ( CH_3-CH=CH_2 ) is...
The carbon-carbon single bond length in propene () is observed to be slightly shorter than the standard C-C single bond length in propane (). Which electronic effect is primarily responsible for imparting this partial double bond character to the single bond in propene?
Options
- AInductive effect
- BElectromeric effect
- CHyperconjugation
- DMesomeric effect
Correct answer
C. Hyperconjugation
Step-by-step solution
In propene (), the alkyl group () is attached to an hybridized carbon atom of the double bond.
The electrons of the C-H bonds in the methyl group undergo delocalization with the adjacent electron system of the double bond. This phenomenon is known as hyperconjugation or no-bond resonance.
Due to this hyperconjugative electron delocalization, the carbon-carbon single bond () acquires a partial double bond character. As a result, the bond length decreases from the standard C-C single bond length of in propane to approximately in propene.
Answer: Hyperconjugation
The electrons of the C-H bonds in the methyl group undergo delocalization with the adjacent electron system of the double bond. This phenomenon is known as hyperconjugation or no-bond resonance.
Due to this hyperconjugative electron delocalization, the carbon-carbon single bond () acquires a partial double bond character. As a result, the bond length decreases from the standard C-C single bond length of in propane to approximately in propene.
Answer: Hyperconjugation