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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

The carbon-carbon single bond length in propene ( CH_3-CH=CH_2 ) is...

The carbon-carbon single bond length in propene (CH3−CH=CH2CH_3-CH=CH_2) is observed to be slightly shorter than the standard C-C single bond length in propane (154 pm154 \text{ pm}). Which electronic effect is primarily responsible for imparting this partial double bond character to the single bond in propene?

Options

  1. AInductive effect
  2. BElectromeric effect
  3. CHyperconjugation
  4. DMesomeric effect

Correct answer

C. Hyperconjugation

Step-by-step solution

In propene (CH3−CH=CH2CH_3-CH=CH_2), the alkyl group (CH3CH_3) is attached to an sp2sp^2 hybridized carbon atom of the double bond.

The σ\sigma electrons of the C-H bonds in the methyl group undergo delocalization with the adjacent π\pi electron system of the double bond. This phenomenon is known as hyperconjugation or no-bond resonance.

Due to this hyperconjugative electron delocalization, the carbon-carbon single bond (C2−C3C_2-C_3) acquires a partial double bond character. As a result, the bond length decreases from the standard C-C single bond length of 154 pm154 \text{ pm} in propane to approximately 150 pm150 \text{ pm} in propene.

Answer: Hyperconjugation
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