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NEET2026ChemistryChapterActual

Consider the following sequence of reactions: Identify the major product 'Z'.

Options

  1. A3-Methylbutan-1-ol
  2. B2,2-Dimethylpropan-1-ol
  3. C2-Methylbutan-2-ol
  4. D3-Methylbutan-2-ol

Correct answer

A. 3-Methylbutan-1-ol

Step-by-step solution

The reaction of 2-methylpropene with HBr in the presence of peroxide follows anti-Markovnikov's rule (Kharasch effect) to give 1-bromo-2-methylpropane (X). ( CH ₃)₂ C = CH ₂ + HBr Peroxide ( CH ₃)₂ CH - CH ₂ Br (X) 1-Bromo-2-methylpropane reacts with magnesium in dry ether to form the corresponding Grignard reagent, isobutylmagnesium bromide (Y). ( CH ₃)₂ CH - CH ₂ Br + Mg dry ether ( CH ₃)₂ CH - CH ₂ MgBr (Y) The Grignard reagent (Y) undergoes nucleophilic addition with formaldehyde (HCHO) followed by acidic hydro

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