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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

Four diatomic species are given below. Which of the following...

Four diatomic species are given below. Which of the following represents the correct sequence of their increasing bond length?

Options

  1. ANO+<NO<O2<O2−\mathrm{NO}^{+} < \mathrm{NO} < \mathrm{O}_2 < \mathrm{O}_2^{-}
  2. BO2−<O2<NO<NO+\mathrm{O}_2^{-} < \mathrm{O}_2 < \mathrm{NO} < \mathrm{NO}^{+}
  3. CNO<NO+<O2−<O2\mathrm{NO} < \mathrm{NO}^{+} < \mathrm{O}_2^{-} < \mathrm{O}_2
  4. DO2<O2−<NO+<NO\mathrm{O}_2 < \mathrm{O}_2^{-} < \mathrm{NO}^{+} < \mathrm{NO}

Correct answer

A. NO+<NO<O2<O2−\mathrm{NO}^{+} < \mathrm{NO} < \mathrm{O}_2 < \mathrm{O}_2^{-}

Step-by-step solution

The bond order of a diatomic species can be determined from its total number of electrons.

For NO+\mathrm{NO}^{+}, the total number of electrons is 7+8−1=147 + 8 - 1 = 14. Its bond order is 33.

For NO\mathrm{NO}, the total number of electrons is 7+8=157 + 8 = 15. Its bond order is 2.52.5.

For O2\mathrm{O}_2, the total number of electrons is 8+8=168 + 8 = 16. Its bond order is 22.

For O2−\mathrm{O}_2^{-}, the total number of electrons is 8+8+1=178 + 8 + 1 = 17. Its bond order is 1.51.5.

Bond length is inversely proportional to bond order. Since the bond order decreases in the sequence NO+>NO>O2>O2−\mathrm{NO}^{+} > \mathrm{NO} > \mathrm{O}_2 > \mathrm{O}_2^{-}, the bond length will increase in the reverse order.

Therefore, the correct sequence of increasing bond length is NO+<NO<O2<O2−\mathrm{NO}^{+} < \mathrm{NO} < \mathrm{O}_2 < \mathrm{O}_2^{-}.

Answer: NO+<NO<O2<O2−\mathrm{NO}^{+} < \mathrm{NO} < \mathrm{O}_2 < \mathrm{O}_2^{-}
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