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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

The third ionisation enthalpy of Lutetium (Lu) is anomalously low....

The third ionisation enthalpy of Lutetium (Lu) is anomalously low. This is primarily attributed to:

Options

  1. Aits exceptionally small atomic radius due to lanthanoid contraction
  2. Bthe attainment of a highly stable completely filled 4f144f^{14} configuration
  3. Cthe strong shielding effect provided by the inner 5d5d electrons
  4. Dits high electronegativity compared to the early lanthanoids

Correct answer

B. the attainment of a highly stable completely filled 4f144f^{14} configuration

Step-by-step solution

The atomic number of Lutetium (Lu) is 7171.

The electronic configuration of Lu is [Xe]4f145d16s2[\text{Xe}] 4f^{14} 5d^{1} 6s^{2}.

During the first and second ionisations, the two 6s6s electrons are removed, forming Lu2+\text{Lu}^{2+} with the configuration [Xe]4f145d1[\text{Xe}] 4f^{14} 5d^{1}.

The third ionisation involves the removal of the single 5d5d electron. This results in the formation of Lu3+\text{Lu}^{3+} with the configuration [Xe]4f14[\text{Xe}] 4f^{14}.

Since the resulting 4f144f^{14} configuration is completely filled and highly stable, the removal of the third electron requires less energy. Thus, the third ionisation enthalpy of Lu is anomalously low.

Answer: the attainment of a highly stable completely filled 4f144f^{14} configuration
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