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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

An alkyl chloride 'X' reacts with magnesium metal in dry ether to...

An alkyl chloride ’X’\text{'X'} reacts with magnesium metal in dry ether to form a Grignard reagent. This Grignard reagent is then treated with solid carbon dioxide, followed by acid hydrolysis, to yield 22-methylpropanoic acid. Identify the alkyl chloride ’X’\text{'X'}.

Options

  1. A11-Chloropropane
  2. B22-Chloropropane
  3. C11-Chloro-22-methylpropane
  4. D22-Chloro-22-methylpropane

Correct answer

B. 22-Chloropropane

Step-by-step solution

The reaction of an alkyl chloride XX (R−ClR-Cl) with magnesium in dry ether forms a Grignard reagent RMgClRMgCl.

R−Cl+Mg→dry etherRMgClR-Cl + Mg \xrightarrow{\text{dry ether}} RMgCl

The Grignard reagent reacts with solid CO2CO_2 followed by acid hydrolysis to form a carboxylic acid RCOOHRCOOH.

RMgCl+CO2→H3O+RCOOHRMgCl + CO_2 \xrightarrow{H_3O^+} RCOOH

The product is given as 22-methylpropanoic acid, which has the structure (CH3)2CH−COOH(CH_3)_2CH-COOH.

Comparing RCOOHRCOOH with (CH3)2CH−COOH(CH_3)_2CH-COOH, the alkyl group RR is the isopropyl group, (CH3)2CH−(CH_3)_2CH-.

Therefore, the alkyl chloride XX is isopropyl chloride, which is 22-chloropropane, (CH3)2CH−Cl(CH_3)_2CH-Cl.

Answer: 22-Chloropropane
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