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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

The α,β -unsaturated ketone shown below is formed as one of the...

The α,β -unsaturated ketone shown below is formed as one of the products in a cross-aldol condensation reaction
The α,β\alpha,\beta-unsaturated ketone shown below is formed as one of the products in a cross-aldol condensation reaction followed by heating.

Identify the pair of reactants that will produce this compound.

Options

  1. APentan-2-one and ethanal
  2. BButan-2-one and propanone
  3. CPentan-3-one and ethanal
  4. DButanal and propanone

Correct answer

B. Butan-2-one and propanone

Step-by-step solution

To identify the reactants that produce the given α,β\alpha,\beta-unsaturated ketone, we can perform a retro-aldol analysis by cleaving the carbon-carbon double bond.

The structure of the given compound is CH3−CH2−C(=O)−CH=C(CH3)2CH_3-CH_2-C(=O)-CH=C(CH_3)_2.

In an aldol condensation, the double bond is formed between the α\alpha-carbon of the enolate (nucleophile) and the carbonyl carbon (β\beta-carbon in the product) of the other reactant (electrophile).

Cleaving the Cα=CβC_{\alpha}=C_{\beta} double bond:
1. The α\alpha-carbon (the −CH=-CH= group adjacent to the carbonyl) gains two hydrogen atoms to form the original ketone. This gives CH3−CH2−C(=O)−CH3CH_3-CH_2-C(=O)-CH_3, which is butan-2-one.
2. The β\beta-carbon (the =C(CH3)2=C(CH_3)_2 group) gains an oxygen atom to form the original carbonyl compound. This gives O=C(CH3)2O=C(CH_3)_2, which is propanone (acetone).

Thus, the cross-aldol condensation between butan-2-one (acting as the enolate at the terminal methyl group) and propanone yields the given product.

Answer: Butan-2-one and propanone
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