NEET 2026
- Exam
- NEET
- Year
- 2026
- Subject
- Chemistry
- Chapter
- Chapter
NEET 2026 · Chemistry · Chapter
The α,β -unsaturated ketone shown below is formed as one of the...
The -unsaturated ketone shown below is formed as one of the products in a cross-aldol condensation reaction followed by heating.
Identify the pair of reactants that will produce this compound.
Options
- APentan-2-one and ethanal
- BButan-2-one and propanone
- CPentan-3-one and ethanal
- DButanal and propanone
Correct answer
B. Butan-2-one and propanone
Step-by-step solution
To identify the reactants that produce the given -unsaturated ketone, we can perform a retro-aldol analysis by cleaving the carbon-carbon double bond.
The structure of the given compound is .
In an aldol condensation, the double bond is formed between the -carbon of the enolate (nucleophile) and the carbonyl carbon (-carbon in the product) of the other reactant (electrophile).
Cleaving the double bond:
1. The -carbon (the group adjacent to the carbonyl) gains two hydrogen atoms to form the original ketone. This gives , which is butan-2-one.
2. The -carbon (the group) gains an oxygen atom to form the original carbonyl compound. This gives , which is propanone (acetone).
Thus, the cross-aldol condensation between butan-2-one (acting as the enolate at the terminal methyl group) and propanone yields the given product.
Answer: Butan-2-one and propanone
The structure of the given compound is .
In an aldol condensation, the double bond is formed between the -carbon of the enolate (nucleophile) and the carbonyl carbon (-carbon in the product) of the other reactant (electrophile).
Cleaving the double bond:
1. The -carbon (the group adjacent to the carbonyl) gains two hydrogen atoms to form the original ketone. This gives , which is butan-2-one.
2. The -carbon (the group) gains an oxygen atom to form the original carbonyl compound. This gives , which is propanone (acetone).
Thus, the cross-aldol condensation between butan-2-one (acting as the enolate at the terminal methyl group) and propanone yields the given product.
Answer: Butan-2-one and propanone