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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

Which of the following is a direct consequence of the lanthanoid...

Which of the following is a direct consequence of the lanthanoid contraction?

Options

  1. AThe basic character of the lanthanoid hydroxides increases steadily from La(OH)3La(OH)_3 to Lu(OH)3Lu(OH)_3.
  2. BThe separation of lanthanoids from their mixture is highly simplified due to significant differences in their chemical properties.
  3. CThe atomic radii of the elements of the second transition series (4d) are almost identical to those of the corresponding elements of the third transition series (5d).
  4. DThe covalent character of the Ln−OHLn-OH bond decreases progressively from La3+La^{3+} to Lu3+Lu^{3+}.

Correct answer

C. The atomic radii of the elements of the second transition series (4d) are almost identical to those of the corresponding elements of the third transition series (5d).

Step-by-step solution

The lanthanoid contraction refers to the steady decrease in atomic and ionic radii across the lanthanoid series due to the poor shielding effect of the 4f4f electrons.

A direct consequence of this contraction is that the atomic radii of the elements of the third transition series (5d5d) become almost identical to those of the corresponding elements of the second transition series (4d4d). For example, the atomic radii of ZrZr (160160 pm)andHfand Hf (159159 pm) are nearly the same.

Regarding the other options:
As the size of the Ln3+Ln^{3+} ion decreases from La3+La^{3+} to Lu3+Lu^{3+}, its polarizing power increases. According to Fajans' rules, this increases the covalent character of the Ln−OHLn-OH bond, which in turn decreases the basic character of the hydroxides from La(OH)3La(OH)_3 to Lu(OH)3Lu(OH)_3.
The separation of lanthanoids is actually very difficult because their similar sizes lead to almost identical chemical properties.

Answer: The atomic radii of the elements of the second transition series (4d) are almost identical to those of the corresponding elements of the third transition series (5d).
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