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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

Assertion (A): Carboxylic acids do not give the characteristic...

Assertion (A): Carboxylic acids do not give the characteristic nucleophilic addition reactions of aldehydes and ketones.
Reason (R): The carbonyl carbon of carboxylic acids is more electrophilic than that of aldehydes and ketones due to the strong electron-withdrawing inductive effect of the −OH-\text{OH} group.

Options

  1. ABoth Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of Assertion (A)
  2. BBoth Assertion (A) and Reason (R) are true but Reason (R) is not the correct explanation of Assertion (A)
  3. CAssertion (A) is true but Reason (R) is false
  4. DBoth Assertion (A) and Reason (R) are false

Correct answer

C. Assertion (A) is true but Reason (R) is false

Step-by-step solution

Carboxylic acids do not undergo characteristic nucleophilic addition reactions like aldehydes and ketones because the lone pair of electrons on the oxygen atom of the −OH-\text{OH} group is involved in resonance with the carbonyl group. This resonance delocalizes the electron density, making the carbonyl carbon less electrophilic (less electron-deficient) compared to the carbonyl carbon in aldehydes and ketones.

Therefore, Assertion (A) is true, but Reason (R) is false because the carbonyl carbon of carboxylic acids is less electrophilic, not more, and this is due to the resonance effect (+R+\text{R}), not just the inductive effect.

Answer: Assertion (A) is true but Reason (R) is false
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