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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

For the thermal decomposition of a gaseous compound, the plot of _...

For the thermal decomposition of a gaseous compound, the plot of log⁡10k\log_{10} k versus 1T\dfrac{1}{T} yields a straight line with a slope of −6.0×103 K-6.0 \times 10^3 \text{ K}. What is the activation energy (EaE_a) for this reaction?

[Given: R=8.314 J K−1 mol−1R = 8.314 \text{ J K}^{-1} \text{ mol}^{-1} and 2.303×8.314=19.15 J K−1 mol−12.303 \times 8.314 = 19.15 \text{ J K}^{-1} \text{ mol}^{-1}]

Options

  1. A49.9 kJ mol−149.9 \text{ kJ mol}^{-1}
  2. B114.9 kJ mol−1114.9 \text{ kJ mol}^{-1}
  3. C21.7 kJ mol−121.7 \text{ kJ mol}^{-1}
  4. D11.5 kJ mol−111.5 \text{ kJ mol}^{-1}

Correct answer

B. 114.9 kJ mol−1114.9 \text{ kJ mol}^{-1}

Step-by-step solution

According to the Arrhenius equation:

k=Ae−Ea/RTk = A e^{-E_a / RT}

Taking logarithm to the base 10 on both sides:

log⁡10k=log⁡10A−Ea2.303RT\log_{10} k = \log_{10} A - \dfrac{E_a}{2.303 RT}

Comparing this with the equation of a straight line y=mx+cy = mx + c, the slope mm of the plot of log⁡10k\log_{10} k versus 1T\dfrac{1}{T} is given by:

m=−Ea2.303Rm = -\dfrac{E_a}{2.303 R}

Given that the slope is −6.0×103 K-6.0 \times 10^3 \text{ K}:

−Ea2.303R=−6.0×103-\dfrac{E_a}{2.303 R} = -6.0 \times 10^3

Ea=6.0×103×2.303×RE_a = 6.0 \times 10^3 \times 2.303 \times R

Substituting the given value of 2.303×R=19.15 J K−1 mol−12.303 \times R = 19.15 \text{ J K}^{-1} \text{ mol}^{-1}:

Ea=6.0×103×19.15 J mol−1E_a = 6.0 \times 10^3 \times 19.15 \text{ J mol}^{-1}

Ea=114900 J mol−1=114.9 kJ mol−1E_a = 114900 \text{ J mol}^{-1} = 114.9 \text{ kJ mol}^{-1}

Answer: 114.9 kJ mol−1114.9 \text{ kJ mol}^{-1}
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