NEET 2026
- Exam
- NEET
- Year
- 2026
- Subject
- Chemistry
- Chapter
- Chapter
NEET 2026 · Chemistry · Chapter
While moving along the inner transition elements, the...
While moving along the inner transition elements, the element-to-element decrease in the ionic radii of ions is observed to be more significant in the actinoid series compared to the lanthanoid series. Which of the following statements correctly explains this observation?
Options
- AThe electrons shield the increasing nuclear charge less effectively than the electrons.
- BThe orbitals are more deeply buried in the atomic core than the orbitals.
- CThe electrons exhibit a weaker penetration effect towards the nucleus than the electrons.
- DThe energy gap between and orbitals is much larger than that between and orbitals.
Correct answer
A. The electrons shield the increasing nuclear charge less effectively than the electrons.
Step-by-step solution
The decrease in ionic radii across the actinoid series (actinoid contraction) is more significant from element to element than the corresponding decrease in the lanthanoid series (lanthanoid contraction).
This occurs because the orbitals are more diffuse and extend further from the nucleus compared to the orbitals. As a result, the electrons shield the increasing nuclear charge less effectively than the electrons.
Due to this poorer shielding by electrons, the effective nuclear charge experienced by the outermost electrons increases more rapidly across the actinoid series, leading to a greater contraction in size.
Answer: The electrons shield the increasing nuclear charge less effectively than the electrons.
This occurs because the orbitals are more diffuse and extend further from the nucleus compared to the orbitals. As a result, the electrons shield the increasing nuclear charge less effectively than the electrons.
Due to this poorer shielding by electrons, the effective nuclear charge experienced by the outermost electrons increases more rapidly across the actinoid series, leading to a greater contraction in size.
Answer: The electrons shield the increasing nuclear charge less effectively than the electrons.