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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

An organic compound, 2,3-dichlorobutane, exhibits stereoisomerism...

An organic compound, 2,3-dichlorobutane, exhibits stereoisomerism due to the presence of chiral carbon atoms. What is the number of optically active isomers and meso forms possible for this compound, respectively?

Options

  1. A4 and 0
  2. B2 and 1
  3. C2 and 2
  4. D3 and 0

Correct answer

B. 2 and 1

Step-by-step solution

The given compound is 2,3-dichlorobutane, whose structure is CH3−CH(Cl)−CH(Cl)−CH3CH_3-CH(Cl)-CH(Cl)-CH_3.

It contains two similar chiral carbon atoms (n=2n = 2). Since the molecule can be divided into two equal halves, it is symmetrical.

For a symmetrical molecule with an even number of chiral centers (nn), the number of optically active isomers is given by a=2n−1a = 2^{n-1}.

Substituting n=2n = 2, we get a=22−1=2a = 2^{2-1} = 2.

The number of meso forms is given by m=2n2−1m = 2^{\dfrac{n}{2}-1}.

Substituting n=2n = 2, we get m=222−1=20=1m = 2^{\dfrac{2}{2}-1} = 2^0 = 1.

Thus, there are 2 optically active isomers (a pair of enantiomers) and 1 meso form.

Answer: 2 and 1
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