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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

For the reaction given below, the equilibrium constant K_c is 8.3 ×...

For the reaction given below, the equilibrium constant KcK_c is 8.3×1038.3 \times 10^3 at 500 K500 \mathrm{~K}.

2Na2O2(s)+2CO2(g)⇌2Na2CO3(s)+O2(g)2\mathrm{Na}_2\mathrm{O}_2(\mathrm{s}) + 2\mathrm{CO}_2(\mathrm{g}) \rightleftharpoons 2\mathrm{Na}_2\mathrm{CO}_3(\mathrm{s}) + \mathrm{O}_2(\mathrm{g})

What is the value of KpK_p for this reaction at the same temperature?
(Given: R=0.083 L bar K−1 mol−1R = 0.083 \mathrm{~L~bar~K^{-1}~mol^{-1}})

Options

  1. A3.4×1053.4 \times 10^5
  2. B2.0×1022.0 \times 10^2
  3. C16.616.6
  4. D8.3×1038.3 \times 10^3

Correct answer

B. 2.0×1022.0 \times 10^2

Step-by-step solution

The given reaction is 2Na2O2(s)+2CO2(g)⇌2Na2CO3(s)+O2(g)2\mathrm{Na}_2\mathrm{O}_2(\mathrm{s}) + 2\mathrm{CO}_2(\mathrm{g}) \rightleftharpoons 2\mathrm{Na}_2\mathrm{CO}_3(\mathrm{s}) + \mathrm{O}_2(\mathrm{g})

The change in the number of moles of gaseous species is Δng=np−nr=1−2=−1\Delta n_g = n_p - n_r = 1 - 2 = -1

The relationship between KpK_p and KcK_c is given by Kp=Kc(RT)ΔngK_p = K_c(RT)^{\Delta n_g}

Substituting the given values:

Kp=8.3×103×(0.083×500)−1K_p = 8.3 \times 10^3 \times (0.083 \times 500)^{-1}

Kp=8.3×10341.5K_p = \dfrac{8.3 \times 10^3}{41.5}

Kp=200=2.0×102K_p = 200 = 2.0 \times 10^2

Answer: 2.0×1022.0 \times 10^2
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