NEET 2026
- Exam
- NEET
- Year
- 2026
- Subject
- Chemistry
- Chapter
- Chapter
NEET 2026 · Chemistry · Chapter
Observe the given reaction schemes for the synthesis of an aromatic...
Observe the given reaction schemes for the synthesis of an aromatic compound X.
Choose the correct option that correctly identifies X, Y, and Z.
Options
- AX = Phenol, Y = Propan-2-one, Z = Benzene diazonium chloride
- BX = Phenol, Y = Propanal, Z = Benzene diazonium chloride
- CX = Benzene, Y = Propan-2-one, Z = Chlorobenzene
- DX = Phenol, Y = Propan-2-one, Z = Nitrobenzene
Correct answer
A. X = Phenol, Y = Propan-2-one, Z = Benzene diazonium chloride
Step-by-step solution
In Scheme 1, the reaction shown is the commercial preparation of phenol from cumene. Cumene (isopropylbenzene) is first oxidized in the presence of air () to form cumene hydroperoxide. This intermediate is then treated with dilute acid () to undergo rearrangement and cleavage, yielding phenol and acetone as a byproduct. Since Y is specified as a ketone, Y is acetone (propan-2-one) and X is phenol.
In Scheme 2, aniline reacts with sodium nitrite () and hydrochloric acid () at low temperatures () to undergo diazotization, forming benzene diazonium chloride. Thus, Z is benzene diazonium chloride. When benzene diazonium chloride is warmed with water, it hydrolyzes to form phenol, which confirms that X is phenol.
Therefore, the compounds are:
X = Phenol
Y = Propan-2-one
Z = Benzene diazonium chloride
Answer: X = Phenol, Y = Propan-2-one, Z = Benzene diazonium chloride
In Scheme 2, aniline reacts with sodium nitrite () and hydrochloric acid () at low temperatures () to undergo diazotization, forming benzene diazonium chloride. Thus, Z is benzene diazonium chloride. When benzene diazonium chloride is warmed with water, it hydrolyzes to form phenol, which confirms that X is phenol.
Therefore, the compounds are:
X = Phenol
Y = Propan-2-one
Z = Benzene diazonium chloride
Answer: X = Phenol, Y = Propan-2-one, Z = Benzene diazonium chloride