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NEET2026ChemistryChapterActual

According to VSEPR theory, which of the following correctly describes the shape of a XeF ₄ molecule and the number of lone pairs of electrons present on its central atom?

Options

  1. ASquare planar shape with two lone pairs
  2. BTetrahedral shape with zero lone pairs
  3. CSee-saw shape with one lone pair
  4. DSquare pyramidal shape with one lone pair

Correct answer

A. Square planar shape with two lone pairs

Step-by-step solution

The central atom is Xenon (Xe). Number of valence electrons in Xe = 8 Number of bonding pairs (bp) with Fluorine atoms = 4 Number of lone pairs (lp) on Xe = 8 - 4 2 = 2 Total number of electron pairs = 4 + 2 = 6 The hybridization is sp^3d^2 and the electron geometry is octahedral. To minimize lone pair-lone pair repulsion, the two lone pairs occupy opposite positions (axial positions). Thus, the molecular shape is square planar with two lone pairs on the central atom. Answer: Square planar shape with two lone pairs

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