Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE MainChemistryAldehydes and Ketones

An unknown carbonyl compound 'X' undergoes reaction with HCN to form a cyanohydrin. This intermediate, upon heating with 95% H ₂ SO ₄ , yields 2-phenylbut-2-enoic acid as the major product. The compound 'X' is:

Options

  1. A1-phenylpropan-1-one
  2. B1-phenylpropan-2-one
  3. C1-phenylethan-1-one
  4. D2-phenylpropanal

Correct answer

A. 1-phenylpropan-1-one

Step-by-step solution

The final product is 2-phenylbut-2-enoic acid, which has the structure CH ₃- CH = C ( C ₆ H ₅)- COOH . Working backwards, the double bond is formed by the dehydration of an -hydroxy acid. Adding water across the double bond places the - OH group at the -carbon, giving 2-hydroxy-2-phenylbutanoic acid, CH ₃- CH ₂- C ( OH )( C ₆ H ₅)- COOH . The - COOH group is formed by the acidic hydrolysis of a nitrile ( - CN ) group. Replacing - COOH with - CN gives the cyanohydrin intermediate, CH ₃- CH ₂- C ( OH )( C ₆ H ₅)- CN

Practice Aldehydes and Ketones on Quantrex Academy →

More from Aldehydes and Ketones

Consider the following reaction. The major product (P) formed is: 2026' x ' is the product which is obtained from benzene by reacting it with carbon monoxide and hydrogen chloride in the presence of cuprous chloride. ' y ' is the major product obtain 2026' x ' is the product which is obtained by the hydrolysis of prop-1-yne in the presence of mercuric sulphate under dilute acidic medium at 333 K. ' y ' is the product which is obtai 2026Given below are two statements: Statement-I: The condensation reaction between CH₃-CH=O and under optimum pH will produce . Statement-II: The molecule will generate Ph-CH=O in the 2026An organic compound " x " where molar ratio of C, O and H are equal, on treatment with 50 % KOH under reflux followed by acidification produced " y ". The most likely structure of 2026Given below are the four isomeric compounds ( P , Q , R , S ) Identify correct statements from below. A. Q , R and S will give precipitate with 2,4- DNP . B. P and Q will give posi 2026Given below are two statements: Statement I : Cross aldol condensation between two different aldehydes will always produce four different products. Statement II : When semicarbazid 2026Which of the following statements are TRUE about Haloform reaction?: A. Sodium hypochlorite reacts with KI to give KOI. B. KOI is a reducing agent. C. , -unsaturated methylketone ( 2026 Full Aldehydes and Ketones list All JEE Main PYQs