JEE MainChemistryBiomolecules
Consider the amino acid given by the structural formula: HOOC - CH ₂- CH ₂- CH ( NH ₂)- COOH . Which of the following statements is correct regarding its physical and chemical properties?
Options
- AIt is highly soluble in non-polar solvents like benzene.
- BIt will have exactly two pK _ a values.
- CIt is a high-melting crystalline solid.
- DIt exists primarily as an anion in highly acidic solutions ( pH < 1 ).
Correct answer
C. It is a high-melting crystalline solid.
Step-by-step solution
The given structure is glutamic acid, an -amino acid. In the solid state and in aqueous solution, it exists as a dipolar zwitterion. Due to strong electrostatic interactions within the zwitterionic structure, it is a high-melting crystalline solid and is insoluble in non-polar solvents like benzene. The molecule has three ionizable groups (two - COOH groups and one - NH ₂ group), so it has three distinct pK _ a values. In highly acidic solutions ( pH Answer: It is a high-melting crystalline solid.