JEE MainChemistryBiomolecules
A naturally occurring disaccharide 'X' does not reduce Fehling's solution and does not exhibit mutarotation. Upon acidic hydrolysis, it yields two different monosaccharides. Identify the disaccharide 'X' and its exact glycosidic linkage.
Options
- AMaltose; linkage between C₁ of -D-glucose and C₄ of -D-glucose
- BSucrose; linkage between C₁ of -D-glucose and C₂ of -D-fructose
- CLactose; linkage between C₁ of -D-galactose and C₄ of -D-glucose
- DSucrose; linkage between C₁ of -D-glucose and C₄ of -D-fructose
Correct answer
B. Sucrose; linkage between C₁ of -D-glucose and C₂ of -D-fructose
Step-by-step solution
The inability to reduce Fehling's solution and the lack of mutarotation indicate that 'X' is a non-reducing sugar. This implies that both anomeric carbons of its constituent monosaccharides are locked in the glycosidic bond. Upon hydrolysis, it yields two different monosaccharides. This points to sucrose (which yields glucose and fructose) rather than a symmetrical non-reducing sugar like trehalose (which yields two glucose units). Sucrose is composed of -D-glucose and -D-fructose. The glycosidic linkage involves t